Abstract
The new compound Ba3Si4P6 crystallizes in the monoclinic system, space group P21/m(No.11) with the lattice constants a = 1153.7(3) pm, b = 728.1(2) pm, c=752.7(2) pm, β = 99.41(5)°. Si4P5 cages are connected by Si chains and P bridges to corrugated two-dimensional nets between which the Ba ions are located. The compound is a Zintl phase and therefore belongs to the valence compounds.
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