B diffusion and activation phenomena during post-annealing of C co-implanted ultra-shallow junctions

Abstract

In order to meet the technological requirements for the next generations of p–n junctions, highly promising methods consist of B and C ultra-low energy co-implantation in Ge pre-amorphized Si. We investigated the B diffusion and the activation phenomena occurring during post-annealing of ultra-shallow junctions (USJ) obtained by spike annealing Si samples pre-amorphized by 20keV Ge and co-implanted with C at 4keV and B at 500eV. Isochronal (60s) post-annealing processes were performed in inert atmosphere (N2) by rapid thermal annealing (RTA) in the 500–1050°C temperature range. We show that, contrary to what reported in the literature about C-free USJ, no B diffusion occurs up to 900°C, and further B clustering is completely suppressed over the whole investigated temperature range. Moreover we observed an increase of the sheet resistance by increasing the temperature up to 900°C followed by a subsequent decrease, that can be easily interpreted on the basis of B diffusion and segregation in native SiO2 and B cluster dissolution. Finally, we show that C significantly reduces up to two orders of magnitude the diffusion coefficient of B, that in our experiments is present in highly extrinsic conditions.