Abstract

Abstract The reaction of 2-phenylazirine (I) with acid chlorides, anhydrides, an imidoyl chloride, and carboxylic acids were investigated. When I was treated with acid chlorides and anhydrides, the corresponding 2, 5-disubstituted oxazole derivatives were obtained. The reaction of I with phthalic and maleic anhydride, however, gave ring-cleavage products. The reaction of I and N-phenylbenzimidoyl chloride gave 1,2, 5-triphenylimidazole. On the other hand, I and benzoic and thiobenzoic acid gave N-benzoylphenacylamine and N-benzoyl-α-benzoylthio-β-aminostyrene respectively.

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