Abstract
The title compound, [Cu(C14H13N2O2)(N3)], is a monomeric neutral complex with one unsymmetrical 6-methoxy-2-(2-pyridylmethyliminomethyl)phenolate Schiff base ligand and one azide ligand. The molecules are connected by a combination of two π–π interactions [centroid–centroid distances 3.359 (3) and 3.378 (2) Å] and one C—H⋯N hydrogen bond into a two-dimensional supramolecular network structure.
Highlights
Xuan SunR factor = 0.028; wR factor = 0.090; data-to-parameter ratio = 16.1
The title compound, [Cu(C14H13N2O2)(N3)], is a monomeric neutral complex with one unsymmetrical 6-methoxy-2-(2pyridylmethyliminomethyl)phenolate Schiff base ligand and one azide ligand
The molecules are connected by a combination of two – interactions [centroid–centroid distances 3.359 (3) and 3.378 (2) Å] and one C—H N
Summary
R factor = 0.028; wR factor = 0.090; data-to-parameter ratio = 16.1. The title compound, [Cu(C14H13N2O2)(N3)], is a monomeric neutral complex with one unsymmetrical 6-methoxy-2-(2pyridylmethyliminomethyl)phenolate Schiff base ligand and one azide ligand. The molecules are connected by a combination of two – interactions [centroid–centroid distances 3.359 (3) and 3.378 (2) Å] and one C—H N hydrogen bond into a two-dimensional supramolecular network structure. Data collection: APEX2 (Bruker, 2004); cell refinement: SAINTPlus (Bruker, 2001); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP (Sheldrick, 1998); software used to prepare material for publication: SHELXL97 and XP.
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