Abstract
The azido complexes [Ti(η5-C5H5Cl2(N3)], [Ti(η5-C5H5)2Cl(N3)], [TiCl(N3)(S2CNEt2)2] and [Ti(N3)(S2CNEt2)3] have been prepared from appropriate metal halides by reaction with trimethylsilylazide. The [Ti(η5-C5H5)Cl2(N3)] complex reacts with HC1 and MeCOCl to give HN3 and MeNCO respectively and [Ti(η5-C5H5)Cl3], whereas [Ti(η5-C5H5)Cl2(NPPh3)] is formed on reaction with PPh3. The phosphiniminato complexes [TiCl(NPPh3)(S2CNEt2)2], [TiCl2(NPPh3)2], [VOCl2(NPPh3)], [VOCl(NPPh3)2] and [VCl3(NPPh3)2] have been prepared from the appropriate halido-complexes and Me3SiN=PPh3.
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