Abstract
The piperidinyl-substituted aluminium azide, [(pip) 2AlN 3] 2 ( 5) (pip = piperidinyl, has been synthesised via the reaction between [(pip) 2AlCl] 2 and one equivalent of NaN 3. A related pyrrolyl derivative, [(Me 2N(H))Al(pyr) 3] ( 7) (pyr = pyrrolyl, was prepared via the dimethylamine elimination reaction between [Al 2(NMe 2) 6] and six equivalents of pyrrole. A third aluminium amido complex, [Li(Al(NH t Bu) 4)] 2 ( 9), has been isolated from the salt elimination reaction between AlCl 3 and an excess of LiNH t Bu. all three compounds have been characterised by X-ray crystallography; compounds 5 and 9 are dimeric in the solid state, whereas 7 is monomeric.
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