Abstract
Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN3 in refluxing ethanol, yielding the title compound, [Ru(η5-C9H7)(N3)(dppe)] or [Ru(C9H7)(N3)(C26H24P2)]. The Ru(II) atom has a typical piano-stool coordination. The Ru—P bond lengths are 2.284 (2) and 2.235 (2) Å. NMR and MS analyses are in agreement with the structure of the title compound.
Highlights
NMR and MS analyses are in agreement with the structure of the title compound
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RN2075)
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
Key indicators: single-crystal X-ray study; T = 200 K; mean (C–C) = 0.010 A; R factor = 0.053; wR factor = 0.096; data-to-parameter ratio = 14.0. Crystal data [Ru(C9H7)(N3)(C26H24P2)] Mr = 656.64 Monoclinic, P21=c a = 11.331 (6) Ab = 14.567 (9) Ac = 17.873 (11) A = 96.015 (19)
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