Abstract
Azatriquinane, an amine with a rigid, hemispherical topology, is synthesized in six steps from pyrrole. It is shown to be more basic than quinuclidine, and can be dimerized by N-oxidation and treatment with base to give novel, highly strained heptacycle. Oxidation with chlorine gives an azatriquinacene, a theoretical precursor to diazadodecahedrane.
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