Abstract
The thermally enhanced photoinduced molecular reorientation based on an axis-selective photo-Fries rearrangement was explored for the first time using three liquid crystalline polymethacrylates with 4-(2′-(4″-methoxyphenyl)ethynyl)phenyl benzoate side groups (1a), 4-methoxybiphenyl benzoate side groups (1b), and 4-methoxyphenyl benzoate side groups (1c). All the polymeric films exhibited an axis-selective formation of the photo-Fries products at the phenyl benzoate derivatives side groups by irradiating with linearly polarized (LP) UV light. Annealing the films in the liquid crystalline temperature range of the material greatly amplified the photoinduced small optical anisotropy of the irradiated films. For 1a and 1b, the photoinduced small anisotropy was amplified in a direction parallel to the polarization (E) of LPUV light and the reorientational order (S) was greater than 0.7. In contrast, the orientation direction was perpendicular to E for 1c (S ∼ 0.57). Finally, a simple double-exposure method usin...
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