Abstract
Abstract Axial preference (>ca. 70% at 25 °C) of alkoxy and silyloxy groups of the chair-type six-membered cyclic compounds has been clarified by the 1H-NMR bandwidth mesurement method. Based on the X-ray analysis of 4-substituted cyclohexanones, it has been disclosed that the cyclohexanone ring adopts chair form and the 4-substituent occupies the axial site in all cases.
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