Abstract

During oxidation of the aluminum- or chromium-substituted magnetites, (Fe 2+Fe 3+ 2− x M 3 f x)O 2− 4, with 0.4 < x < 1.8 in defect phase γ of the same spinel structure, the availability for oxidation of Fe 2+ ions in the tetrahedral sites (A sites) of the spinel structure is much less than that in octahedral sites (B sites) and in both cases depends on the extent of aluminum or chromium substitution. The influence of cation distribution in A and B sites on the oxidation temperature is shown directly by differential thermogravimetric analysis and by electrical conductivity.

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