Abstract

Phosphorus fixation results in low P use efficiency in acid soils. Increase in soil pH through urea hydrolysis may improve P availability and use efficiency. Growth chamber and field experiments were conducted to evaluate effects of urea on triple superphosphate (TSP) transformation and P use efficiency. A Ste. Rosalie clay (Typic Humaquept), an Ormstown silty clay loam (Typic Humaquept) and a Chicot sandy clay loam (Typic Hapludalf) were used in the growth chamber experiment with three rates of N (0, 200 and 400 mg N kg-1), two N sources, either urea or NH4 NO3, based on 87 mg P kg-1 soil. In the field, three rates of urea (0, 60 and 120 kg N ha-1) and two rates of TSP (26 and 52 kg P ha-1) were compared on a Ste. Rosalie clay and an Ormstown silty clay loam. Compacted or blended mixtures of urea-TSP with different ratios of N:P were used in the field experiment. In the growth chamber experiment, soil pH and dissolved organic carbon (DOC) concentration was increased by added urea, and Mehlich (3) and water extractable P thus increased with increased urea. Soil pH, DOC and available P levels were not significantly affected by added NH4 NO3. Phosphorus uptake increased with added N, either urea or NH4 NO3, but P concentration increased only with addition of urea. In the field, soil Mehlich (3)-P at day 20, P uptake and use efficiency, corn yields increased when urea was applied with TSP. Compacted mixtures of urea-TSP increased P uptake and use efficiency, corn yields in comparison with blended mixtures. The beneficial effects of banded urea with TSP on P availability and P use efficiency were primarily attributed to urea hydrolysis, subsequent pH increase and organic matter dissolution as well as synergistic effect of N and P. These results indicate that compaction of urea plus TSP may offer a significant advantage over blended mixtures.

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