Abstract

Gallium-based liquid metal alloys have been attracting attention from both industry and academia as soft, deformable, reconfigurable and multifunctional materials in microfluidic, electronic and electromagnetic devices. Although various technologies have been explored to control the morphology of liquid metals, there is still a lack of methods that can achieve precise morphological control over a free-standing liquid metal droplet without the use of mechanical confinement. Electrochemical manipulation can be relatively easy to apply to liquid metals, but there is a need for techniques that can enable automatic and precise control. Here, we investigate the use of an electrochemical technique combined with a feedback control system to automatically and precisely control the morphology of a free-standing liquid metal droplet in a sodium hydroxide solution. We establish a proof-of-concept platform controlled by a microcontroller to demonstrate the reconfiguration of a liquid metal droplet to desired patterns. We expect that this method will be further developed to realize future reconfigurable liquid metal-enabled soft robots.

Highlights

  • Gallium-based liquid metal alloys, such as Eutectic Gallium Indium (EGaIn, 75% gallium and 25% indium) [1] and Galinstan (68.5% gallium, 21.5% indium, and 10% tin) [2], have been gaining momentum in recent years as promising soft-matter electronics and multifunctional materials [3,4,5]

  • In comparison to mercury (Hg), the most commonly known liquid metal, liquid metal alloys based on gallium have much lower toxicity [8], making them much safer to use for research and commercial purposes

  • In order to overcome the aforementioned challenge, we proposed the use of a feedback control system combined with electrochemical techniques to manipulate the morphology of an EGaIn droplet within sodium hydroxide (NaOH) solution in a simple, fast, automatic and precise manner

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Summary

Introduction

Gallium-based liquid metal alloys, such as Eutectic Gallium Indium (EGaIn, 75% gallium and 25% indium) [1] and Galinstan (68.5% gallium, 21.5% indium, and 10% tin) [2], have been gaining momentum in recent years as promising soft-matter electronics and multifunctional materials [3,4,5]. Unlike mercury, gallium-based liquid metal alloys can form a thin oxide layer on the surface [9], enabling these metals to be patterned or re-configured into useful shapes, such as micro- or nano-sized droplets [10,11,12,13]. The shape of liquid metals can be manipulated by electrochemical deposition or removal of the oxide layer on its surface to decrease or increase the interfacial tension, precise automatic control over the morphology is still challenging.

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