Automated radioanalytical determination of lead and beryllium

Abstract

The automated modification of the radioanalytical determination of lead and beryllium using AutoAnalyzer modules has been developed. The method for lead determination is based on a two-phase isotope exchange of lead between the sample solution labelled with212Pb and the standard lead diethyldithiocarbamate solution in carbon tetrachloride. For the determination of beryllium a substoichiometric isotope dilution method using7Be as tracer and acetylacetone in chloroform as extractant was used. As little as 0.02 μg/ml of lead and 2 μg/ml of beryllium can be determined by the methods above. The flow diagrams of the automated procedures are presented.