Abstract
A two-dimensional photoelectron spectrum of NO has been measured in the photon energy range of 10.7–13.4eV. The spectrum exhibits many salient features due to autoionization. The vibrational distribution for NO + ( X 1∑ +) is simulated by means of Franck-Condon analysis, using a harmonic or anharmonic potential energy curve for the autoionizing state. The vibrational levels of this state are substantially perturbed by the Rydberg states converging to NO + ( X 1∑ +).
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