Autoignition of Hydrogen / Natural Gas / Nitrogen Fuel Mixtures at Reheat Combustor Operating Conditions

Abstract

Previous autoignition studies at conditions relevant to reheat combustor operation have indicated that the presence of relatively small amounts of natural gas (NG) in H2/N2 fuel significantly changes the autoignition behavior. The present study further elucidates the influence of NG on autoignition, kernel propagation, and subsequent flame stabilization at conditions that are relevant for the practical operation of gas turbine reheat combustors (p = 15 bar, Tinlet > 1000 K, hot flue gas, appropriate residence times). The experimental investigation was carried out in a generic, optically accessible reheat combustor. Autoignition events in the mixing zone were recorded by a high-speed camera at frame rates of up to 30,000 fps. This paper describes the autoignition behavior as the H2 volume fraction is increased (decreasing NG) in a H2/NG/N2 fuel mixture for two different jet penetration depths. Additionally, the subsequent flame stabilization phenomena and the structure of the stabilized flame are discussed. The results reveal that autoignition kernels occurred even for the lowest H2 fuel fraction, but they did not initiate a stable flame in the mixing zone. Increasing the H2 volume fraction decreased the distance between the initial position of the autoignition kernels and the fuel injector, finally leading to flame stabilization. The occurrence of autoignition kernels at lower H2 volume fractions (H2/(H2+NG) < 85%) was not found to be significantly influenced by the fluid dynamic and mixing field differences related to the different jet penetration depths. In contrast, autoignition leading to flame stabilization was found to depend on jet penetration; flame stabilization occurred at lower H2 fractions for the higher jet penetration depth (H2/(H2+NG) ≈ 89 compared to H2/(H2+NG) ≈ 95 vol. %).