Autocatalytic duplex Ni–P/Ni–W–P coatings on AZ31B magnesium alloy

Abstract

Autocatalytic duplex Ni–P/Ni–W–P coatings were deposited on AZ31B magnesium alloy using stabilizer free nickel carbonate bath. Some of the coated specimens were passivated in chromate solution with and without heat treatment. Plain Ni–P coatings were also prepared for comparison. Coatings were characterized for their surface morphology, composition and corrosion resistance. Energy dispersive analysis of X-ray (EDX) showed that the phosphorous content in the Ni–P coating is 6wt.% and for Ni–W–P it reduced to 3wt.% due to the codeposition of tungsten in the Ni–P coating. Marginal increase in P and W contents was observed on passivated coupons along with Cr (0.18wt.%) and O (2.8wt.%) contents. Field emission scanning electron microscopy (FESEM) examination of these coating surfaces exhibited the nodular morphology. Chromate passivated surfaces showed the presence of uniformly distributed bright Ni particles along with nodules. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) studies were carried out in deaerated 0.15M NaCl solution to find out the corrosion resistance of the coatings. Among the coatings developed, duplex-heat treated-passivated (duplex-HTP) coatings showed lower corrosion current density (icorr) and higher polarization resistance (Rp) indicating the improved corrosion resistance. The charge transfer resistance (Rct) value obtained for the duplex-HTP was about 170 times higher compared to that for Ni−P coating.