Abstract
The Autler–Townes (AT) splitting in femtosecond photoelectron spectrumof three-level Li2 molecules is theoretically investigated usingtime-dependent quantum wave packet method. With proper femtosecondlaser pulses, three peaks of the AT splitting can be observed in thephotoelectron spectrum. The AT splitting stems from rapid Rabioscillation caused by intense ultrashort laser pluses. The effects oflaser parameters on the molecular ionization dynamics are alsodiscussed.
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