Abstract
合成了一系列(1,1'-联苯)-2-二(1-金刚烷基)磷配体,并制备出8种相应的Au(Ⅰ)配合物.以甲醇为溶剂,在6-十二炔水合反应中考察了8种Au(Ⅰ)配合物的催化性能,结果表明,以含有3'-(吡咯-1-羰基)官能团的Au(Ⅰ)配合物为催化剂时,其用量仅需炔烃用量的0.1%~0.3%(摩尔分数),室温下即可高效地催化炔烃进行水合反应.
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