Abstract
Ion bombardment of SiO2 produces an understoichiometric surface layer containing a distribution of bonding states: SiO2, SiO x and free Si. Under the electron beam probe, a redistribution occurs, favoring the SiO2 and free Si states at the expense of SiO x , without loss of oxygen. The free Si yield exhibits the same energy dependence as the Auger yield of the Si LVV transition, thus pointing to Auger-induced bond rupture as the primary damaging event.
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