Abstract
CO2-selective photoreduction to value-added products is ideal, but its practical application suffers from weak photogenerated carrier separation and insufficient multielectron transport. Herein, we constructed the tricomponent AuNPs@SnO2-AuNCs hybrid by decorating Au nanoclusters (AuNCs) on the Au nanoparticle (AuNPs)@SnO2 core-shell structure. AuNC-NP dual coupling endowed AuNPs@SnO2-AuNCs with an excellent CO yield of 64.8 μmol g-1 h-1 during CO2 photoreduction, which was higher than the role of separate application of AuNCs (25.3 μmol g-1 h-1) and AuNPs (16.0 μmol g-1 h-1). It was mainly attributed that the coaction of AuNPs and AuNCs not only enhanced the visible light absorption capacity but also improved the photogenerated carrier separation/migration. As a result, the electron-rich AuNCs induced from plasmonic AuNPs and photoexcited SnO2 promoted the photocatalytic CO2-to-CO performance. This work provides a new perspective to design multicomponent photocatalysts for highly efficient CO2 conversion.
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