Abstract

The synthesis of the mixed polymer [TBPcGeO] n containing phthalocyaninatogermanium (PcGe) and tetrabenzoporphyrinatogermanium (TBPGe) subunits linked by oxygen bridges, is reported. Iodine doping leadi to [TBPcGeOI 1.1] n at the maximum doping level, which shows a room temperature d.c. conductivity σ RT = 8 × 10 −2 S/cm.

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