Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis‐[Re(CH3CN)2Cl4]·CH3CN and cis‐[Re(NHC(OCH3)CH3)2Cl4

Peter C Kunz,Bernhard Spingler,Roger Alberto,Philipp Kurz

doi:10.1002/zaac.200700265

Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis‐[Re(CH3CN)2Cl4]·CH3CN and cis‐[Re(NHC(OCH3)CH3)2Cl4

Peter C Kunz, Bernhard Spingler + Show 2 more

https://doi.org/10.1002/zaac.200700265

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Journal: Zeitschrift für anorganische Chemie	Publication Date: Oct 29, 2007
Citations: 4

Affiliation: University of Zurich, Heinrich Heine University Düsseldorf, Uppsala University

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Abstract

AbstractThe abstraction of the halogenide ligands in [Re(CH3CN)2Cl4]− should result in a solvent‐only stabilized ReIII complex. The reactions of salts of [Re(CH3CN)2Cl4]− with silver(I) and thallium(I) salts were investigated and the solid‐state structures of cis‐[Re(CH3CN)2Cl4]·CH3CN and cis‐[Re(NHC(OCH3)CH3)2Cl4] are described.

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