Atrazine and its metabolites in surface and well waters in rural area and its human and ecotoxicological risk assessment of Henan province, China

Abstract

ABSTRACTA study to monitor atrazine (ATR) and its metabolites in surface and well waters in rural area of Henan province was undertaken. A total of 66 surface water and 38 well water samples were collected during the period from July to August in 2016. The residues of ATR and its metabolites, such as desethylatrazine (DEA), deisopropylatrazine (DIA), and hydroxyatrazine (HA) were analyzed by UPLC-MS/MS. The detection rate of ATR and its metabolites under different pH values was investigated. Based on the survey results, a human health non-carcinogenic and carcinogenic risk assessment was conducted for adults and children. Ecotoxicological risk assessment was also conducted using default endpoint values and the risk quotient method. The results showed that ATR and DEA were the most frequently detected substances, the detection rate of which were 75.0 and 60.6%, respectively, and the level of ATR and its metabolites in this research was in the mid-range when compared with other countries. The detection rate of ATR and DEA in alkali water was much higher than that in acid water. ATR posed low potential non-carcinogenic risk to human through the exposure route of drinking water, and showed acceptable carcinogenic risk estimates for adults and children both in median and highest concentration. Ecotoxicological risk of ATR and DEA assessment revealed acceptable risk.