ATR-FTIR spectroscopy and chemometric techniques for determination of polymer solution viscosity in the presence of SiO2 nanoparticle and salinity.

Abstract

An analytical method was proposed for quantitative determination of rheological properties of polyacrylamide (PAM) solution in the presence of SiO2 nanoparticle and NaCl. The viscosity of PAM-SiO2 nanohybrid solution was predicted using attenuated total reflection Fourier-transform infrared (ATR-FTIR) spectroscopy in the wavenumber range of 800-3000 cm-1 and chemometrics methods. Support vector machine regression (SVM-R) as a non-linear multivariate calibration procedure and partial least squares regression (PLS-R) as a linear procedure were applied for calibration. Preprocessing methods such as baseline correction and standard normal variate (SNV) were also utilized. Root mean square error of prediction (RMSEP) in SNV-SVM and SNV-PLS methods were 3.231 and 6.302, respectively. Considering the complexity of the samples, the SVM-R model was found to be reliable. The proposed method is rapid and simple without any sample preparation step for measurement of the viscosity of polymer solutions in chemical enhanced oil recovery (CEOR).