Abstract

HighlightsX-ray photoelectron spectroscopy results confirmed the increased number of M–N sites in the bimetallic Fe–Co catalyst.Synchrotron-based X-ray absorption fine structure demonstrated that the interaction in the coordination environments of the different transition metal sites facilitated the CO production in electroreduction reaction of CO2 (ECO2RR).This bimetallic strategy has also been extended to fabricate other catalysts such as Cu–Co and Ni–Co, which also exhibited enhanced performance for ECO2RR.

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