Abstract

Light scattering proceeding through electric and magnetic dipole absorption events (E1–M1) exhibits natural circular dichroism, widely used in the characterization of chiral media, and the magneto-chiral effect, which is under consideration as a mechanism for the homo-chirality of life. Additional manifestations of E1–M1 scattering are resonance enhanced Bragg diffraction and non-reciprocal linear dichroism. In spite of its established importance for a raft of significant phenomena, there has not been a complete treatment of E1–M1 light scattering by electrons. Starting from the interaction that includes both electron spin and angular momentum variables, we construct scattering that proceeds via a spin–orbit split intermediate state for the photo-ejected electron. Employing new relations for re-coupling angular momentum we give a theoretical basis for the derivation of sum-rules for integrated dichroic signals. In order to assist in the interpretation of the algebraic terms present for E1–M1 we construct ...

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