Atomic structure and magnetic properties of Cu 80Co 20 nanocrystalline compound produced by mechanical alloying

Abstract

Direct observation of the atomic structure of the mechanically alloyed Cu 80Co 20 compounds has been made using the field ion microscope (FIM). Phase composition, defect structure and morphology of material on the atomic scale have been determined. It has been established that the studied material is chemically inhomogeneous, presenting a mixture of two main phases: heterogeneous solid solution of cobalt in copper, and pure cobalt. Phase volume ratios, particle and cluster sizes have been estimated. An evaluation of Co content in CuCo solid solution has been made. The width of interfaces in this mechanically alloyed material was revealed to be at least twice the width of phase boundaries in metals and alloys. Superparamagnetism of the compound studied at elevated temperatures and saturation magnetization deficit at low temperatures are discussed on the basis of the above-mentioned structural data.