Abstract
The work is devoted to application of a high sensitive and precise method of atomic resonance absorption spectroscopy for the measurements of the time profiles of concentration of various halogen atoms (chlorine, bromine, iodine), formed in pyrolysis of relevant inhibitors of combustion (CCl4, C2F4Br2, CF3I). The experiments were performed at temperatures of 1000–2000 K and a pressure of 2–3 bar behind reflected shock waves. In results the rate constants of dissociation of C2F4Br2, CF3I and their activation energy were measured.
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