Abstract
This letter reports about crystal structure, lattice relaxation, synthesis, and phase stability of BN–C and GaP–Si solid solution crystals. The hypothesis of atomic pair substitution is discussed and x-ray diffraction (XRD) proof is provided for the replacement of A IIIB V atomic pairs with C IV pairs. Cubic BN–diamond solid solutions underwent lattice relaxation after phase transformation leading to atomic displacement disorder.
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