Abstract
This paper constitutes a theoretical study of the influence of interstitial impurity atoms on the type of order-disorder transition in an alloy of the AB3-Cin type with an hcp structure. Allowance is made for a variety of types of interstices over the range 0 ≤η 1. The free energy is calculated by the Gorskii-Bragg-Williams method. In the presence of an impurity there may be a change in the magnitude of the jump taking place in the degree of long-range order at the transition point, and also a change in the type of order-disorder transition occurring.
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