Abstract
The first stages of diamond growth on scratched silicon substrates were studied by atomic force microscopy (AFM). Samples were obtained by both hot filament and microwave plasma CVD methods at short deposition times prior to coalescence. It was observed that, after an incubation time, diamond nanocrystals nucleated onto the scratches produced by diamond paste polishing. The Raman spectra of the crystals showed different bands associated with several carbon phases. Simultaneous with diamond growth, we detected an etching effect of the silicon surface attributed to the atomic hydrogen present in the activated gas.
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