Atomic “After Effects” Following181Hfβ--Decay

Abstract

Strong evidence of atomic “after effects” following β−-decay of 181Hf was observed from perturbed angular correlation (PAC) studies in different viscous and non-viscous molecular solutions and in ionic as well as non-ionic solutions. In non-viscous acetone and H2O solutions, the PAC spectra have been found to be completely different to what was expected considering molecular motions in these media. Similarly, in the glycerol-H2O system, PAC spectra remain significantly unchanged with the change of viscosity indicating that molecular motions are not reflected in these media. Rather, perturbations from the interaction of the nucleus-excited atomic state, which was so far considered to be absent for 181Hf β−-decay, have been found to be dominant. The atomic shell recovery times in molecular liquids have been found to be in the range 50–150 nsec. In insulating solid HfCl4 medium, however, the PAC spectrum indicates that the atomic shell following 181Hf β−-decay remains unchanged within the lifetime of the intermediate state. The lifetime for the 615 keV level has been remeasured and a value of T1/2=12.1±0.1 nsec only has been obtained. This value, although in strong disagreement with the earlier reported value (17.83 μsec), helps explain atomic “after effects” in 181Hf β−-decay.