Atmospheric Lead in Antarctic Ice during the Last Climatic Cycle

Abstract

Concentrations of lead (Pb) have been measured by the ultra-clean isotope dilution mass spectrometry technique in various sections of the Antarctic Dome C and Vostok deep ice cores, whose ages range from 3.85 to 155 ka B.P., in order to assess the natural, pre-human, sources of this toxic heavy metal in the global troposphere. Pb concentrations were very low, as low as about 0.3 pg Pb/g during the Holocene and probably during the last interglacial and part of the last ice age. On the other hand, they were quite high, up to about 40 pg Pb/g, during the Last Glacial Maximum and at the end of the penultimate ice age. Wind-blown dust from crustal rock and soil appears to be the main natural source of Pb in the global troposphere. Pb contribution from volcanoes is significant during periods of low Pb only. Contribution from the oceans is insignificant.