Atmospheric fallout of radionuclides in peat bogs in the Western Segment of the Russian Arctic.

Abstract

This article presents the results of studies of the activity of radionuclides in peat-bog profiles of the European subarctic of Russia. Two peat profiles were collected in different areas of the Arkhangelsk region. The peat cores were used to determine 210Pb, 137Cs, 241Am, 239Pu, 240Pu, 238U, and 234U content. To estimate the relationship between radionuclide activity and physicochemical parameters of peat, the content of organic matter, water-soluble salts, carbonates and ash, and the pH of aqueous and salt extracts were studied. Radionuclide activity concentrations in peat samples were measured using inductively coupled plasma mass spectrometry (ICP-MS), low-background semiconductor gamma spectrometry with a high-purity germanium (HPGe) detector, and alpha spectrometry. The 210Pb chronology of peat cores was studied using a constant flow model based on the Monte Carlo simulation method. Comparison of 210Pb dating data showed that the position of the maximum activity peaks of anthropogenic radionuclides shifted along the peat profile. This is probably due to the relative mobility of different radionuclides in the peat massif. Measurement of the atomic ratio 240Pu/239Pu showed that the main sources of pollution in the peatlands of the European subarctic of Russia are global fallout from atmospheric tests from the 1950s through 1980 and fallout from the Chernobyl nuclear accident in 1986. This study shows that a complex of radioactive isotopes in peat deposits can provide valuable information on the environmental pollution loads of subarctic territories.