Atmospheric black carbon in urban and traffic areas in Shanghai: Temporal variations, source characteristics, and population exposure

Abstract

Black carbon (BC) measurements were performed at Pudong (PD) urban supersite and Gonghexin (GH) roadside station from December 1, 2017 to August 10, 2020 to investigate the variations, source characteristics, and population exposure levels of BC in traffic and urban areas in Shanghai, China. The BC median concentration at GH was more than two-fold that at PD. Absorption Ångström exponent (AAE) values were 1.27 ± 0.17 and 1.31 ± 0.17 at PD and GH, respectively, suggesting the dominance of liquid fossil fuel combustion sources (i.e., traffic exhaust) at these stations. The higher BC and AAE values in winter at PD indicated the relatively increasing contribution of solid fuels (i.e., biomass burning) to BC concentration in urban Shanghai. The diurnal variation in BC showed similar twin-peak patterns at PD and GH, implying that traffic emission mainly contributed to ambient BC concentration in urban Shanghai. The estimated daily intakes (EDIs) of BC were generally higher in males than in females at both PD and GH. The highest BC EDIs at PD were found in age subgroups 1–<2 and 2–<3 years. In contrast, the BC EDIs at GH were observed in age subgroups 6–<9, 12–<15, and 15–<18 years, which were higher than those determined at PD, indicating that more attention must be paid to BC exposure of the population in these age subgroups. These results provide scientific insights into variations, source characteristics, and population exposure levels of BC in urban and traffic areas and could help in the development of BC control strategies in Shanghai.