An asymmetrically coordinated Zn-Co diatomic site catalyst for efficient hydrogen evolution reactions.

Abstract

We propose an innovative preparation method, namely, a two-step pyrolysis process, to synthesize Zn-Co bimetallic catalysts with excellent hydrogen evolution performance. In the synthesized Zn1Co1-SNC catalyst, there exists a strong interaction between Zn and Co, along with synergistic effects with S/N atoms, collectively promoting the stability of the catalyst structure. Experimental results demonstrate that the overpotential of this catalyst at 10 mA cm-2 current density is only 49 mV, and it maintains excellent hydrogen evolution performance even after 5000 cycles.