Abstract
Chiral arsinooxazoline Ru(II) complex has been found to be an efficient catalyst for asymmetric transfer hydrogenation of aromatic ketones in 2-propanol. Secondary alcohols with up to 94% enantiomeric excess were obtained at a substrate/catalyst mole ratio of 1000:1. Asymmetric kinetic resolution has also been obtained with 1-arylalkanols at room temperature with 99% ee.
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