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Abstract
The total synthesis of halicholactone by using the chirality of (diene)Fe(CO) 3 complexes was reported. The key steps of the synthesis include catalytic asymmetric alkylation, regio- and stereoselective phenylsulfenylation, regio- and stereoselective cyclopropanation and formation of a nine-membered lactone by ring-closing metathesis.
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