Abstract
Asymmetric induction into meso-1,3-diacetoxy-5-cycloheptene 4 by PFL-catalyzed hydrolysis afforded monoacetate (1S,3R)- 5 of 96% enantiomeric excess (e.e), which was converted into a synthetic equivalent 14 of the δ-lactone moiety in mevinic acid derivatives.
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