Abstract
The first synthesis of an optically active 1-phenylphospholane-2-carboxylic acid–borane complex and a 1-phenylphosphorinane-2-carboxylic acid–borane complex, which are proline and pipecolic acid phosphorous analogues, has been accomplished. The key to the synthesis is the enantioselective deprotonation accompanied with diastereoselective carboxylation.
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