Abstract
AbstractP-Stereogenic secondary phosphine oxides [SPOs, RR′P(O)H], valuable ligands for metal complexes in asymmetric catalysis, are also building blocks for other chiral phosphorus derivatives. This short review summarizes methods used for asymmetric synthesis of P-stereogenic SPOs.1 Introduction2 Configurational Stability of P-Stereogenic SPOs3 Classical Resolution, HPLC Separation, and Dynamic Resolution4 Synthesis via Chiral Auxiliaries5 Kinetic Resolution6 Conclusions and Outlook
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