Abstract
Abstract A short, efficient and general route for the preparation of o.p. alkyl and aryl sulfinates is described. Both epimers at sulfur can be obtained using DAG as unique inductor of chirality and, only by choosing the adequate base (Py or i-Pr2NEt), the configuration at sulfur can be predicted. The efficiency of this methodology has been demonstrated by the synthesis of o.a. alkyl aryl and dialkyl sulfoxides with high e.e. (up to 100%).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Phosphorus, Sulfur, and Silicon and the Related Elements
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
