Abstract
AbstractThe asymmetric Pudovik reaction of chiral fluoroalkyl α,β‐unsaturated ketimines derivated from (R)‐tert‐butanesulfinamide and diphenyl phosphite was achieved in the presence of Rb2CO3 at room temperature. A series of fluoroalkylated α‐amino phosphonates were prepared in good yields with high diastereoselectivities.
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