Abstract
High-resolution Raman measurements were performed on the $^{14}\mathrm{N}_{2}$ vibrons and the $^{15}\mathrm{N}_{2}$ internal vibration in mixed crystals of \ensuremath{\alpha}-${(}^{15}$${\mathrm{N}}_{2}$${)}_{0.013}$${(}^{14}$${\mathrm{N}}_{2}$${)}_{0.937}$${\mathrm{Ar}}_{0.05}$. In contrast to what was assumed for the analysis of previous time-resolved coherent anti-Stokes Raman-scattering measurements, asymmetric line shapes are found. We relate the asymmetry to inhomogeneous broadening resulting from perturbations of the perfect lattice structure by the Ar substitution. We discuss the consistency of these frequency-domain results with those of previous time-resolved measurements and finally show how the asymmetry is contained in the time domain.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
