Asymmetric induction radical copolymerization of optically active l‐menthyl vinyl ether with vinylene carbonate and indene

Abstract

AbstractThe copolymerizations of l‐menthyl vinyl ether (l‐MVE) with the monomers vinylene carbonate (VCA) and indene (IN) were carried out in benzene with azobisisobutyronitrile (AIBN) as an initiator to obtain optically active copolymers. The optically active l‐menthyl residue from the copolymer main chain was removed using dry hydrogen bromide gas. After the ether cleavage reaction, the copolymers prepared (VA–VCA and VA–IN) were still optically active, and hence it was found that asymmetric induction had taken place in the copolymer main chain. The optical rotatory dispersion (ORD) and circular dichroism (CD) data of the original and ether‐cloven copolymers were also determined.