Abstract
AbstractThe reaction of alkenyl glycosides 2a–2c with MCPBA gives diasteroisomeric mixtures of epoxides 3 and 4. The asymmetric induction decreases in the order 2a ≫ 2b > 2c. The absolute configuration of epoxyalkyl glycosides is determined by correlation with (R)‐glycerinaldehyde in an independent synthesis of 3a and 3c.
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