Abstract
A new chiral tridentate ligand containing two phosphines and one pyridine is effective for Ru-catalyzed asymmetric hydrosilylation of simple ketones (47–66% ee). Ruthenium complexes with either chiral tridentate nitrogen ligands or chiral bidentate phosphorus ligands are either inactive or non-selective for asymmetric hydrosilylation. This work has set a foundation for the asymmetric catalytic reactions based on chiral mixed PN tridentate ligands.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
