Abstract
Abstract Asymmetric hydroformylation of styrene is performed using dinuclear thiolato bridged rhodium complexes with BDPP as the chiral auxiliary ligand. The optical yields observed depend on the starting organometallic complex. When (+) and (−) dithiolate bridged complexes and (+) and (−) diphosphine are combined, there is one pair which enhances the enantioselectivity.
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