Abstract
Enantiomerically pure 2,5-diorganocyclopentanecarboxylic acids bearing a non-stereogenic, chirotopic center were prepared via stereoselective copper catalyzed carbon-carbon bond forming reactions. These compounds serve as intermediates in the synthesis of new chiral monoalkylboranes which lead to enantio-selectivities of up to 64% ee in the asymmetric hydroboration of cyclic olefins.
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